The influence of the spacer Z on N-phosphorylated bis-thioureas and 2,5-dithiobiurea Z[C(S)NHP(O)(OiPr)2]2 (Z = NHCH2CH2NH, NHC6H4-2-NH, NHNH) crystal design

Two new bifunctional N-phosphorylated thioureas and a 2,5-dithiobiurea of the common formula Z[C(S)NHP(O)(OiPr)2]2 [Z = NHCH2CH2NH (1), NHC6H4-2-NH (2), NHNH (3)] have been synthesized and characterized by NMR spectroscopy and single crystal X-ray diffraction. The structure of the compound 3 has been studied in CDCl3 and DMSO-d6 solutions.

Two new bifunctional N-phosphorylated thioureas and a 2,5-dithiobiurea of the common formula Z[C(S)NHP(O)(OiPr)2]2 [Z = NHCH2CH2NH (1), NHC6H4-2-NH (2), NHNH (3)] have been synthesized and characterized by NMR spectroscopy and single crystal X-ray diffraction. The structure of the compound 3 has been studied in CDCl3 and DMSO-d6 solutions.Figure optionsDownload as PowerPoint slide