کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1340831 979757 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
1D MnIII–FeII heterometallic coordination polymer built by an approach of metalloligand
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
1D MnIII–FeII heterometallic coordination polymer built by an approach of metalloligand
چکیده انگلیسی

1D heterometallic coordination polymer of [(FeII(L)2)(MnIII(salen))(ClO4) · 2CH3CN · CH3OH] (1 · 2CH3CN · CH3OH) has been built through a metalloligand approach (L = hydrotris (1,2,4-triazolyl)borate). Ferrous [FeII(L)2] moiety can be easily incorporated into further extended networks by the facile reduction of ferric antiprismatic [FeIII(L)2]+ metalloligand due to the reducing ability of borate ligands during the reaction. And more, hydroquinone facilitates the reduction. Therefore, we present single crystal X-ray structure analysis of 1 · 2CH3CN · CH3OH along with X-ray absorption spectroscopy to confirm the reduction of iron centres.

1D heterometallic coordination polymer comprising of [MnIII(salen)] and ferrous moiety [(FeII(L)2)] generated by the reduction of [(FeIII(L)2)]+ has been built to be a [(FeII(L)2)(MnIII(salen))(ClO4)] (1) through a metalloligand approach, whether L stands for hydrotris(1,2,4-triazolyl)borate.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 26, Issue 4, 1 March 2007, Pages 929–932
نویسندگان
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