Manganese (III) fluoride as a new synthon in Mn cluster chemistry

The syntheses and structures of five new Mn3+ clusters [Mn26O17(OH)8(OMe)4F10(Bta)22(MeOH)14(H2O)2] (1), [Mn10O6(OH)2(Bta)8(py)8F8] (2), {NHEt3}2[Mn3O(Bta)6F3] (3), [Mn8O4(OMe)2(Me2Bta)6F8(Me2BtaH)(MeOH)8] (4), and [Mn13O12(Me2Bta)12F6(MeOH)10(H2O)2] (5), are reported, thereby demonstrating the utility of MnF3 as a new synthon in Mn cluster chemistry.

The syntheses and structures of five new Mn3+ clusters are reported, thereby demonstrating the utility of MnF3 as a new synthon in Mn cluster chemistry.Figure optionsDownload as PowerPoint slide