کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1374770 981924 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
N-confused porphyrin possessing glucamine-appendants: Aggregation and acid/base properties in aqueous media
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
N-confused porphyrin possessing glucamine-appendants: Aggregation and acid/base properties in aqueous media
چکیده انگلیسی

A water-soluble derivative of N-confused porphyrin (NCP: 5,10,15,20-tetraaryl-2-aza-21-carbaporphyrin) was synthesized by introducing glucamine groups at the para-position of meso-aryl groups. The tetraglucamine-appended NCP (TG-NCP) exists as monocation in aqueous solution containing 6 mM sodium dodecyl sulfate (SDS) but exists as freebase to form aggregates in pure water. These properties are distinct from those of corresponding regular porphyrin, which exists as freebase in the micellar solution and practically insoluble in water.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Bioorganic & Medicinal Chemistry Letters - Volume 18, Issue 24, 15 December 2008, Pages 6394–6397
نویسندگان
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