کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1429286 | 987168 | 2011 | 4 صفحه PDF | دانلود رایگان |
Interfacial assembly of sandwich mixed (phthalocyaninato)(porphyrinato) rare earth triple-decker complexes [(Pc)Eu(Pc)Eu(TPyP)] (1) and [(TPyP)Sm(Pc)Sm(TPyP)] (2) (Pc = phthalocyaninate, TPyP = meso-tetrakis(4-pyridyl)porphyrinate) has been comparatively studied at the air/pure water and the air/CdCl2 aqueous solution subphase interfaces. Surface pressure-area isotherms revealed the remarkable increase of limiting mean molecular area of the triple-deckers with the presence of Cd2+, suggesting the occurrence of in situ interfacial coordination. The formation of coordination bonds between the pyridyl groups of TPyP macrocycles in the triple-deckers and Cd2+ ions from the subphase was further supported by FT-IR spectroscopic data. Electronic absorption measurements showed the formation of J-aggregates of the triple-decker molecules in the interfacial assembled films.
Journal: Materials Science and Engineering: C - Volume 31, Issue 5, 20 July 2011, Pages 950–953