Material- and process-effects on homogeneity and electric properties of transparent conducting films composed of hydrazine-reduced graphene oxide and/or silver nanowire

• h-rGO films prepared by spin-coating are more homogeneous than those by dip-coating.
• Large-sized h-rGO(NiSiNa) films prepared with a rotation number of 2000 rpm had wrinkles.
• Larger ratio of pyrrolic nitrogen to oxygen-bound nitrogen gave smaller WF values.
• Mechanical pressing at 100 °C made the thickness of AgNW films small.
• The arithmetic average roughness of h-rGO/AgNW/Cytop film was 1.2 nm.

Photomicroscope observation of hydrazine-reduced graphene oxide (h-rGO) films indicates that the films prepared by spin-coating are more homogeneous than those prepared by dip-coating. Graphene oxide (GO) is apt to aggregate during the dipping process. Increasing rotation speed of the spin-coating decreased film thickness and increased surface resistant (Rs). Rs of small-sized h-rGO(BF1A) was smaller than that of large-sized h-rGO(NiSiNa). The h-rGO(NiSiNa) films prepared with a rotation number smaller than 2000 rpm had wrinkles about 5 nm in height and particles with about 15 nm height. The rotation number of 3000 rpm decreased the wrinkles and particles resulting in smaller Rs. Increasing the hydrazine-treatment temperature from 90 to 140 °C caused the Rs values to decrease. Work-function values of h-rGO(NiSiNa) were 3.6–3.8 eV; smaller than those of other h-rGOs. Larger ratio of pyrrolic nitrogen to oxygen-bound nitrogen gave smaller WF values. Silver nanowire (AgNW) films prepared by multiple spin-coating processes showed small Rs vales and small Rs deviations. Mechanical pressing at 100 °C made the thickness of AgNW films equal to the AgNW diameter and decreased the Rs values. Polymer (Cytop) was coated on the AgNW films and the h-rGO/AgNW/Cytop transparent conducting film was peeled off. The arithmetic average roughness of the h-rGO surface was 1.2 nm.

Figure optionsDownload as PowerPoint slide