کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1441955 | 1509429 | 2011 | 6 صفحه PDF | دانلود رایگان |
Improved synthesis and reinvestigation of the magnetic properties of triphenylamine bearing three nitronylnitroxide radicals (1) were carried out. Single crystal X-ray crystallographic analysis of 1 established that its molecular shape had a C3-symmetry. Our newly prepared 1 showed different physical properties from those of reported. SQUID measurements of 1 showed that each of the three spins of 1 behaved independently at room temperature. In contrast, the three spins coupled antiferromagnetically at lower temperature as low as ca. 1.8 K. These spin behaviors can be explained by a regular triangular antiferromagnetic model (J/kB = −3.3 K) and interpreted as a spin frustration system.
► We synthesized a triradical and reinvestigated its magnetic properties.
► The triradical has a C3-symmetrical molecular shape.
► The triradical showed different physical properties from those of reported.
► Tree spins on the triradical interact antiferromagnetically each other.
► The magnetic behavior was interpreted as a spin frustration system.
Journal: Synthetic Metals - Volume 161, Issues 15–16, August 2011, Pages 1557–1562