کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1442460 1509451 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
In situ synthesis and characterization of polyaniline–CaCu3Ti4O12 nanocrystal composites
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد بیومتریال
پیش نمایش صفحه اول مقاله
In situ synthesis and characterization of polyaniline–CaCu3Ti4O12 nanocrystal composites
چکیده انگلیسی

High dielectric constant (ca. 2.4 × 106 at 1 kHz) nanocomposite of polyaniline (PANI)/CaCu3Ti4O12 (CCTO) was synthesized using a simple procedure involving in situ polymerization of aniline in dil. HCl. The PANI and the composite were subjected to X-ray diffraction, Fourier transform infrared, thermo gravimetric, scanning electron microscopy and transmission electron microscopy analyses. The presence of the nanocrystallites of CCTO embedded in the nanofibers of PANI matrix was established by TEM. Frequency dependent characteristics of the dielectric constant, dielectric loss and AC conductivity were studied for the PANI and the composites. The dielectric constant increased as the CCTO content increased in PANI but decreased with increasing frequency (100 Hz–1 MHz) of measurement. The dielectric loss was two times less than the value obtained for pure PANI around 100 Hz. The AC conductivity increased slightly up to 2 kHz as the CCTO content increased in the PANI which was attributed to the polarization of the charge carriers.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Synthetic Metals - Volume 159, Issues 19–20, October 2009, Pages 2128–2134
نویسندگان
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