کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1443898 | 1509482 | 2006 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis of 2-phenylquinoline-based ambipolar molecules containing multiple 1,3,4-oxadiazole spacer groups Synthesis of 2-phenylquinoline-based ambipolar molecules containing multiple 1,3,4-oxadiazole spacer groups](/preview/png/1443898.png)
A series of donor–acceptor type ambipolar electroluminescence dyes with the general structure PQ(OXD)nT (where n = 1, 2 and 3) were prepared, in which PQ is 2-phenylquinoline, T is diphenylamine which constituted the hole transporting triphenylamine moiety with an adjacent phenyl ring, and OXD is an electron transporting 2-phenyl-1,3,4-oxadiazole repeating unit. The compounds fluoresced bluish green to green hue in solid-state, exhibited a positive solvatochromism in solution and their quantum efficiency decreased rapidly with increase in n. The materials are thermally stable with glass transition temperature (Tg) ranging from 83 °C (n = 1) to 130 °C (n = 3). Cyclic voltammetry studies indicated the HOMO remained relatively unchanged with n while the LUMO decreased (away from the vacuum level) with an increase in the number of OXD. For single layer homojunction OLEDs, highest efficiency was obtained when n = 1 (max luminous 3300 cd/m2 and current efficiency 0.9 cd/A), whereas for multilayer heterojunction OLEDs, best results was achieved for compounds with n = 1 or 2 assuming the role of the HT layer (over 8200 cd/m2 max and 2.0 cd/A). Formation of exciplexes led to significant red-shift and lower emission efficiency for the compound with n = 3.
Journal: Synthetic Metals - Volume 156, Issues 2–4, 1 February 2006, Pages 270–275