کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1458549 | 989579 | 2016 | 8 صفحه PDF | دانلود رایگان |
A series of Eu3+- or Dy3+-doped and Eu3+/Dy3+ co-doped Y2WO6 in pure phase was synthesized via high-temperature solid-state reaction. X-ray diffraction, diffuse reflection spectra, photoluminescence excitation and emission spectra, the CIE chromaticity coordinates and temperature-dependent emission spectra were exploited to investigate the phosphors. Upon UV excitation at 310 nm, efficient energy transfer from the host Y2WO6 to dopant ions in Eu3+ or Dy3+ single-doped samples was demonstrated and those phosphors were suitable for the UV LED excitation. The intense red emission was observed in Y2WO6: Eu3+, and blue and yellow ones were observed in Y2WO6: Dy3+. Concentration quenching in Y2WO6: Dy3+ phosphors could be attributed to the electric dipole-dipole interaction. In Eu3+/Dy3+ co-doped Y2WO6 phosphors energy transfer process only took place from the host to Eu3+/Dy3+ ions and warm white-light emission can be obtained by adjusting the dopant concentrations. The temperature-dependent luminescence indicated Eu3+/Dy3+ co-doped Y2WO6 was thermally stable. Our overall results suggested that Y2WO6: Ln3+ (Ln3+=Eu3+, Dy3+) as warm white-light emitting host-sensitized phosphor might be potentially applied in WLEDs.
Journal: Ceramics International - Volume 42, Issue 12, September 2016, Pages 13841–13848