کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1458576 | 989579 | 2016 | 8 صفحه PDF | دانلود رایگان |
In this work, the diphosphate compound, RbFeP2O7, was prepared by the conventional solid-state reaction. The X-ray diffraction pattern revealed that the sample presents a single phase, that crystallizes in the monoclinic structure with a P21/C space group. Impedance analysis was performed using the equivalent circuit model, and, it indicated the presence of intra- and inter-granular contribution. Furthermore, the electrical conductivity, the dielectric properties and the relaxation behavior of this material were studied in detail using the impedance spectroscopy technique, in a frequency ranging from 200 Hz to 5 MHz at several temperatures. The temperature dependency of frequency exponent 's' shows that the correlated barrier-hopping model (CBH) is the most responsible mechanism for AC conduction in the investigated compound. In terms of CBH model, the values of maximum barrier s height, the hopping distance and the density of localized states are determined and discussed. A correlation between electrical and structural properties was also discussed.
Journal: Ceramics International - Volume 42, Issue 12, September 2016, Pages 14041–14048