کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1459002 989588 2016 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Acrylamide route for the co-synthesis of tungsten carbide–cobalt nanopowders with additives
ترجمه فارسی عنوان
مسیر آکریل آمید برای همکاری سنتز نانوپودر کبالت با افزودنی های کاربید تنگستن
کلمات کلیدی
کاربید تنگستن کبالت، نانو پودر، کارابید وانادیوم، هیدروژل، منبع کربن در محل
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
چکیده انگلیسی

In this work, cemented tungsten carbide nano-particles were prepared by a chemical method called acrylamide gel. In this process, first, a xerogel containing tungsten and cobalt oxide particles was synthesized. Then, it was carburized by a hydrogen reduction heating process.Acrylamide and N, N-methylene-bis-acrylamide monomers were used as an in-situ carbon. Ammonium meta tungstate (NH4)6H2W12O40·xH2O, and cobalt nitrate Co(NO3)2·6H2O salts were used as the precursor.Both reduction and carburization reactions were carried out simultaneously and the formation of the intermediate phases of W2C, Co3W3C, and Co6W6C led to decrease in the activation barrier.Transactions of reduction and carburization processes were studied by X-ray diffraction analysis at various temperatures. Accordingly, tungsten carbide phase formation was completed at 1100 °C. The formation of W–C and V–C bonds was verified by Raman spectroscopy. SEM images showed the average nano particle size of 50 nm.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 42, Issue 8, June 2016, Pages 9382–9386
نویسندگان
, , , ,