کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1460154 989601 2015 15 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation, thermal stability and magnetic properties of new AgY1−xGdx(WO4)2 ceramic materials
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Preparation, thermal stability and magnetic properties of new AgY1−xGdx(WO4)2 ceramic materials
چکیده انگلیسی

Polycrystalline samples of α-AgY1−xGdx(WO4)2 with x=0, 0.005, 0.01, 0.025, 0.05, 0.1, 0.2, and 1 have been prepared by a solid state reaction method and the influence of Gd3+ substitution for Y3+ on microstructure, thermal and magnetic properties was investigated. The X-ray diffraction analysis showed the phases to crystallize in the monoclinic symmetry, space group C2/m. A reversible monoclinic to tetragonal phase transition occurs in AgY1−xGdx(WO4)2 and strongly depends on Gd3+ ion concentration. Electron paramagnetic resonance (EPR) spectra of Gd3+ ions showed non-monotonous dependence of interaction strength on gadolinium concentration. Magnetic measurements showed paramagnetic behavior and strong increase of magnetic moment as the yttrium content decreases.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 41, Issue 4, May 2015, Pages 5734–5748
نویسندگان
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