Microstructure stabilization of a novel glass/YSZ composite coating material by adding alumina particles

Glass-based composite coating materials incorporating particles of alumina or YSZ were prepared by reaction sintering. It was revealed that phase evolution played a key role on thermal expansion behavior of the composite coating materials. Both precipitating of t-ZrO2 crystals and adding YSZ inclusions could raise CTEs of the glass-based matrix, while the formation of zircon produced the reverse effect. Especially, alumina additives retarded the crystallization of the base glass and reduced reaction rates between YSZ and the glass matrix remarkably. Thus, the Al2O3/YSZ/glass tri-composites could serve as an environmental barrier coating for intermetallics and superalloys because of the stabilized microstructure.