کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1461500 | 989620 | 2014 | 9 صفحه PDF | دانلود رایگان |
Copper incorporated zinc oxide (CuZnO) thin films were synthesized onto the glass and tin doped indium oxide (ITO) coated glass substrates at 450 °C by simple and cost-effective spray pyrolysis technique (SPT). The X-ray diffraction (XRD) patterns confirmed the polycrystalline nature of the films having hexagonal crystal structure. A compact and granular morphology was observed for all deposited films. The absorption edge of the CuZnO films showed a red shift, meaning that the optical band gap energy decreases as copper doping concentration increases. The room-temperature photoluminescence (PL) spectra of CuZnO films revealed the ultraviolet (UV) near band edge emission peak at ~373 nm and the defect related level emission at ~447 nm. Furthermore, films deposited onto conducting ITO coated glass substrates were tested for their photoelectrochemical (PEC) performance in 0.5 M Na2SO4 electrolyte solution. The fill factor (FF) and open circuit voltage (Voc) values were improved for CuZnO films.
Journal: Ceramics International - Volume 40, Issue 6, July 2014, Pages 7669–7677