کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1461641 | 989621 | 2013 | 5 صفحه PDF | دانلود رایگان |
In order to develop multiferroics with large magnetization and polarization, we have prepared a series of (1−x)[0.9BiFeO3–0.1DyFeO3]–xPbTiO3 [BDF–xPT] solid solution ceramics by solid state reaction. X-ray diffraction reveals that, with the increase of PbTiO3 concentration, the solid solution transforms from a rhombohedral to a tetragonal phase with the presence of a morphotropic phase boundary (MPB) region located at 0.28≤x≤0.40 at room temperature, in which the rhombohedral, tetragonal and orthorhombic phases coexist. The temperature dependence of the dielectric permittivity indicates that the Curie temperature decreases with the increasing amount of PbTiO3. Based upon the structural analysis and dielectric characterization, a preliminary phase diagram for the BDF−xPT pseudo-binary system has been proposed. It is found that the ceramics of compositions around the MPB exhibits much better dielectric properties with dielectric constant of the BDF–0.37PT ceramics reaching 459 at 1 kHz, confirming the beneficial effects of the MPB on the dielectric performance.
Journal: Ceramics International - Volume 39, Supplement 1, May 2013, Pages S207–S211