کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1463431 | 989647 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Influence of VO2 nanostructured ceramics on hydrogen desorption properties from magnesium hydride
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
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چکیده انگلیسی
The hydrogen desorption properties and kinetics of MgH2-VO2 composite prepared by mechanical milling of MgH2 and VO2 have been investigated. Structural characterization of produced nanocomposite was done by X-ray powder diffraction (XRD), particle size analysis and scanning electron microscopy (SEM). The structure and morphology of the composite have been correlated with hydrogen desorption properties investigated by differential thermal analysis (DTA). It has been shown that short mechanical milling of nanostructured VO2 and MgH2 leads to decrease of hydrogen desorption temperature of MgH2 by 80Â K. The mechanism of desorption has been changed from phase boundary reaction, spherical symmetry for untreated MgH2 to phase boundary reaction, cylindrical symmetry for the composite material. The activation energy for desorption has been reduced by adding VO2 ceramics as a catalyst.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 39, Issue 1, January 2013, Pages 51-56
Journal: Ceramics International - Volume 39, Issue 1, January 2013, Pages 51-56
نویسندگان
Sanja MiloÅ¡eviÄ, Željka RaÅ¡koviÄ-Lovre, Sandra Kurko, Radojka Vujasin, Nikola CvjetiÄanin, Ljiljana MatoviÄ, Jasmina GrboviÄ NovakoviÄ,