کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1463679 989650 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The characteristics of Ni–Co–Mn–O precursor and Li(Ni1/3Co1/3Mn1/3)O2 cathode powders prepared by spray pyrolysis
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
The characteristics of Ni–Co–Mn–O precursor and Li(Ni1/3Co1/3Mn1/3)O2 cathode powders prepared by spray pyrolysis
چکیده انگلیسی

Ni–Co–Mn–O precursor powders with spherical shape and dense structure were prepared by spray pyrolysis from a spray solution containing a drying control chemical additive (DCCA) and polymeric precursors. In contrast, the Ni–Co–Mn–O precursor powders obtained from a spray solution without additives had a hollow and porous morphology. Ni–Co–Mn–O precursor powders with a spherical shape and dense structure yielded Li(Ni1/3Co1/3Mn1/3)O2 cathode powders with a spherical shape and fine size by means of a solid-state reaction with lithium hydroxide. The mean size of the spherical cathode powder was 1.1 μm. The discharge capacity of the Li(Ni1/3Co1/3Mn1/3)O2 powders with spherical shape and filled morphology was 195 mA h g−1 at a current density of 0.1 C. The discharge capacities of the cathode powders with spherical shape and filled morphology at 55 °C decreased from 183 to 154 mA h g−1 by the 30th cycle at a current density of 0.5 C.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 35, Issue 3, April 2009, Pages 1205–1210
نویسندگان
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