Synthesis of lanthanum beta-alumina powders by the polymeric precursor technique

La-β-Al2O3 (LaAl11O18) powders were synthesized by the polymeric precursor technique using lanthanum nitrate and aluminum nitrate. The transformations during thermal treatment of the precursor solution with ethylene glycol and citric acid were evaluated by thermal analysis. Fourier transform infrared spectroscopy analysis was performed after calcinations of the polymeric resin for determination of residual carbon. The specific surface area was evaluated by the BET method. Fine powders with ∼121 m2/g specific surface area and 20 nm average particle size were obtained and observed by scanning and transmission electron microscopy. Nearly single phase LaAl11O18 was obtained after pressing and sintering these powders at 1600 °C with small additions of MgO. The sintered pellets were characterized by X-ray diffraction and scanning electron microscopy. Impedance spectroscopy measurements carried out in the 1000–1200 °C range show the electrolytic behavior of the La-β-Al2O3 pellets, suggesting their application as solid electrolytes in high temperature potentiometric oxygen sensors.