Effects of annealing on phase evolution, microstructure and magnetic properties of mechanically synthesized nickel-ferrite

The influence of milling and subsequent annealing on nickel-ferrite phase formation was investigated by X-ray diffraction (XRD). Microstructure and magnetic properties of NiFe2O4 were determined by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and vibration sample magnetometry (VSM). Single phase nanosized nickel-ferrite was obtained by 30 h mechanical alloying (MA) and subsequent annealing at 600 °C for 1 h. Magnetic properties of the milled powder were extensively affected by the annealing temperature. Considerable growth of the particles and necking by sintering resulted from annealing at 1000 °C.