کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1465234 989684 2009 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structural anomaly and electrical relaxation in (Na2/3Pb1/3)(Mn1/2Nb1/2)O3 ceramics
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Structural anomaly and electrical relaxation in (Na2/3Pb1/3)(Mn1/2Nb1/2)O3 ceramics
چکیده انگلیسی

The X-ray diffraction patterns of (Na2/3Pb1/3)(Mn1/2Nb1/2)O3 ceramics were measured within 15–850 K temperature range. The anomaly in the thermal expansion temperature dependence occurred in 250–365 K range. The generalised Cole–Cole model was proposed to describe the measured effective electric permittivity influenced by high electric conduction and the coexistence of two contributions ɛ*(T,f) = ɛ*lattice + ɛ*carriers was considered. The analysis of the electric permittivity and conduction exhibited two relaxation processes. The electric conduction relaxation characteristic time values indicated the small polaron mechanism with τ0 ≈ 10−13 s occurring in 240–345 K range and the ionic mechanism with τ0 ≈ 10−11 s involved in the other relaxation occurring in the 320–510 K range. The ionic relaxation process was ascribed to a subsystem of defects, which was weakly interrelated to the anomaly in thermal expansion of the (Na2/3Pb1/3)(Mn1/2Nb1/2)O3 ceramics. The Gate model was proposed to describe the ionic relaxation mechanism.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 35, Issue 6, August 2009, Pages 2357–2366
نویسندگان
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