The inhibition effect of Azure A on mild steel in 1 M HCl. A complete study: Adsorption, temperature, duration and quantum chemical aspects

In this study, inhibition effect of Azure A on mild steel in 1.0 M HCl were evaluated by using electrochemical impedance spectroscopy (EIS), linear polarization resistance (LPR), and potentiodynamic polarization and scanning electron microscope (SEM) methods. These studies were carried out at different concentrations, temperatures and durations. The inhibitor molecules were chemisorbed on electrode surface according to the Langmuir adsorption isotherm. The quantum chemical calculations were employed to give further insight into the inhibition mechanism of Azure A.

► Azure A molecule is found to be a good inhibitor for mild steel in HCl solution.
► SEM results clearly indicate that a protective film formation occurred on the mild steel surface.
► The long term corrosion tests are cleared that the Azure A has effectively protected the mild steel in HCl solution.
► The quantum chemical measurements were cleared the reactive sites and charges of atoms in the molecule.