کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1470370 | 990323 | 2005 | 7 صفحه PDF | دانلود رایگان |

Sodium diethyldithiocarbamate (DDTC) self-assembled monolayer (SAM) on copper surface has been investigated by SERS and EDS and the results show that DDTC SAM is chemisorbed on copper surface by its S atoms with tilted orientation. Corrosion inhibition ability of DDTC SAM was measured in 3% NaCl solution using electrochemical methods. The impedance results indicate that the maximum inhibition efficiency of DDTC SAM can reach 99%. Quantum chemical calculations show that DDTC has relatively small ΔE between HOMO and LUMO and large negative charge in its two sulfur atoms, which facilitates the formation of a DDTC SAM on copper surface.
Research highlights
► DDTC is of low toxicity.
► DDTC SAM had good corrosion inhibition effects on copper in 3% NaCl solution.
► DDTC SAM was chemisorbed on copper surface by its S atoms.
Journal: Corrosion Science - Volume 53, Issue 5, May 2011, Pages 1999–2005