Evaluation of the bactericidal characteristics of nano-copper oxide or functionalized zeolite coating for bio-corrosion control in concrete sewer pipes

The bactericidal characteristics of nano-copper oxide or functionalized zeolite coated concrete pipes against Acidithiobacillus thiooxidans were studied by measuring the temporal variation of bacterial dry cell weight measurement, cellular Adenosine Triphosphate production, as well as oxygen uptake rate of the aforementioned bacterium. Uncorroded (UC), severely corroded (SC), and moderately corroded (MC) concrete pipes were electrochemically coated with a nano-copper oxide, while another uncorroded concrete pipe was used to apply functionalized zeolite coating (Z2). Specimens were characterized by field emission-scanning electron microscopy, and optical microscopy. Oxygen uptake rate of the bacterium was the highest in UC followed by the MC. Oxygen uptake rate and cellular Adenosine Triphosphate decreased progressively in Z2 and SC throughout the duration of the experiment due to decline in live bacterial cell. The maximum bacterial specific growth rate was 1.1 × 10−2 day−1 for both UC and MC, with a decay rates varying from 1.4 × 10−2 to 2.6 × 10−2 day−1. The minimum concentration limits for the inhibition of the bacterium in the nano-copper oxide coated concrete pipes ranged from 2.3 mg to 2.6 mg Cu per mg dry cell weight.