کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1470547 990328 2010 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of water chemistry on the corrosion mechanism of a zirconium–niobium alloy in simulated light water reactor coolant conditions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Influence of water chemistry on the corrosion mechanism of a zirconium–niobium alloy in simulated light water reactor coolant conditions
چکیده انگلیسی

The oxidation of the zirconium alloy E110 inf simulated nuclear power plant coolant at 310 °C is characterised using in situ Electrochemical Impedance Spectroscopy (EIS) and ex-situ microscopic observations. EIS data have been fitted to a transfer function derived from the Mixed Conduction Model. The kinetic parameters characterising the oxidation process – interfacial rate constant of oxidation, diffusion coefficient of oxygen vacancies, and field strength in the inner layer – have been estimated. The dependence of their values on LiOH/KOH/NaF content are discussed in terms of an enhanced rate of dissolution of the barrier layer at higher level of alkali and fluoride.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Corrosion Science - Volume 52, Issue 1, January 2010, Pages 54–67
نویسندگان
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