Corrosion behaviour of laser gas nitrided Ti–6Al–4V in HCl solution

Laser surface nitriding of Ti–6Al–4V alloy was carried out with a Nd:YAG pulsed laser. The microstructure and corrosion behaviour of the nitrided samples were examined, using SEM, XRD, XPS, and anodic polarization tests in 2 M HCl solution. Laser nitriding produced a thin continuous TiN layer followed by TiN dendrites and TiN0.3 needles. The laser nitrided specimen exhibited less corrosion current density, passivated more readily and also, maintained a lower current density over the duration of the experiment. This was correlated with the formation of very thin, continuous TiNxOy film, which could retard chloride ions ingress into the substrate.