کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1472134 | 990371 | 2006 | 23 صفحه PDF | دانلود رایگان |
Corrosion-induced copper runoff has been monitored for copper sheet, naturally patinated copper and pre-patinated copper, with and without surface treatments, in a marine environment during one year. The study comprises solution measurements on total copper runoff rates, sulphates and chlorides released from the patina, and parallel surface analytical studies on patina formation, combined with electrochemical impedance measurements on changes in barrier properties during exposure. Bioassay tests and model predictions were applied to elucidate copper bioavailability at the immediate release situation. The runoff rate of copper was significantly lower compared to the corrosion rate throughout the exposure period. At comparable rain quantities, copper runoff rates were significantly lower at the marine site compared to similar data obtained in an urban environment. The bioavailable concentration of released copper was significantly lower compared to the total copper concentration.
Journal: Corrosion Science - Volume 48, Issue 12, December 2006, Pages 4316–4338