Electrophoretic deposition of hydroxyapatite nanostructured coatings with controlled porosity

Hydroxyapatite (HA) coatings with controlled porosity were prepared by electrophoretic deposition (EPD) method. Carbon black (CB) particles were used as the sacrificial template (porogen agent). Two component suspensions containing different concentrations of HA and CB particles were prepared in isopropanol. It was found that the finer and positively charged HA nanoparticles are heterocoagulated on the coarser and negatively charged CB particles to form CB–HA composite particles with net positive charge. The deposition rate from the suspensions with WR (CCB/CHA ratio) of 0.25 was faster than that of those with WR: 0.5 at initial times of EPD. However the situation was reversed at longer EPD times. It was also found that the amount of porosity in the coatings increases as the CB concentration in the suspension increases (15%, 24%, 31%, 43% for the coatings deposited from the suspensions with 20 g/L HA nanoparticles and 0, 5, 10 and 20 g/L CB particles, respectively).