کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1476568 991156 2011 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Environmental durability of slurry based mullite–gadolinium silicate EBCs on silicon carbide
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Environmental durability of slurry based mullite–gadolinium silicate EBCs on silicon carbide
چکیده انگلیسی

Water vapor oxidation and salt corrosion resistances of mullite–gadolinium silicate (Gd2SiO5) environmental barrier coatings (EBCs) dip coated on α-SiC substrates and sintered to 1430 °C/3 h in air were investigated. The EBC exhibited excellent adherence to the substrate during thermal cycling between 1350 °C and room temperature (RT) for 100 h in a simulated lean combustion environment (90% H2O–balance O2),11, 13 and 15 forming ∼10 μm porous silica layer at coating-substrate interface, compared to ∼17 μm for uncoated α-SiC exposed under same conditions. The EBC did not spall after a 24 h 1200 °C exposure in Na2SO4 corrosion environment leading to further coat densification. However, after 48 h salt exposure, the EBC showed severe through-thickness cracks, and cavities and de-lamination at coating-substrate interface. The corrosion gaseous products such as CO2, CO and SO2 trapped under a low viscosity glassy (Na2O·x(SiO2)) liquid phase were formed due to salt vapor reaction with α-SiC substrate created these cavities.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 31, Issue 6, June 2011, Pages 1123–1130
نویسندگان
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