کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1479025 | 991241 | 2005 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Pressure-induced low symmetry phases in Ti-rich lead zirconate titanate PbZr0.20Ti0.80O3
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The titanium-rich PZT solid solution PbZr0.20Ti0.80O3 was studied under high pressure by X-ray diffraction and Raman spectroscopy. A series of low-symmetry phases were observed, including monoclinic (space groups Cm and Cc) and triclinic forms (space groups F 1 and F1¯) in PbZr0.20Ti0.80O3. High pressure Raman spectra obtained are consistent with a monoclinic (Cc)–triclinic (F1) phase transition involving a soft mode at 9 GPa, in agreement with the change in compressibility detected by X-ray diffraction. The strong Raman spectra observed in the paraelectric phase can also be explained by the triclinic F1¯ symmetry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 25, Issue 12, 2005, Pages 2393–2396
Journal: Journal of the European Ceramic Society - Volume 25, Issue 12, 2005, Pages 2393–2396
نویسندگان
J. Rouquette, J. Haines, V. Bornand, M. Pintard, Ph. Papet, F.A. Gorelli,