کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1481062 | 1510449 | 2014 | 8 صفحه PDF | دانلود رایگان |
• A new glass, phosphate–borate glasses doped Er, is prepared by the melt-quenching technique.
• We have studied the effect of adding borate to phosphate glass, doped with concentration of Er.
• Thermal behavior and the optical absorption for our samples are studied.
• We have described the relationship between the optic properties and the factor (Ω4/Ω6).
In this paper a set of (95-x) P2O5–xB2O3–4.9Na2O–0.1Er2O3 (x = 5–10–15–20 mol%) samples was prepared using a conventional melt-quenching technique. A glass ceramic phase was confirmed by X-ray diffraction. Small crystallites at the B2O3 addition were detected by Raman scattering. The glass containing 20 mol% B2O3 shows a high thermal stability with a value ΔT = Tc–Tg exceeding 100 °C, where Tg and Tc are the glass transition and crystallization onset temperatures. The Raman spectroscopy measurement shows that BOP bonds were present in the glasses.From the absorption edge studies, the value of the optical band gap Eopt has been evaluated. The decrease in optical band gap values and consequently the decrease in Urbach's energies confirm the less extension of the localized states within the band gap. As a result, there shall be an increase in the order of the glass network. The variation in optical parameters is owing to the substitution of B2O3 oxides in P2O5–Na2O–Er2O3 glass network. The fundamental absorption edge for all the glasses was analyzed and the Judd–Ofelt parameters (Ω2, Ω4 and Ω6) were obtained. The PL intensity, the PL life time and the quantum efficiency relative to the 4I13/2 → 4I15/2 (1530 nm) transition of Er3 + were all found to decrease with the addition of B2O3.
Journal: Journal of Non-Crystalline Solids - Volume 389, 1 April 2014, Pages 38–45