کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1483380 991593 2010 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of the polymer architecture on the high temperature behavior of SiCO glasses: A comparison between linear- and cyclic-derived precursors
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Influence of the polymer architecture on the high temperature behavior of SiCO glasses: A comparison between linear- and cyclic-derived precursors
چکیده انگلیسی

Two series of cross-linked polysiloxanes, precursors for silicon oxycarbide glasses, have been synthesized from a linear and a cyclic Si–H-containing siloxane having the same chemical formula (SiCOH4). The crosslinking has been achieved by hydrosilylation reaction with various amounts of divinylbenzene (DVB). A detailed structural characterization has been performed by 29Si and 13C MAS NMR, FT-IR and chemical analysis. As a result, two different structural models have been proposed for the two series of resins. The two resins have been pyrolyzed at 1400 °C and the resulting SiCO ceramics characterized by X-ray diffraction. It has been shown that the stability of the amorphous silica phase present in the SiCO ceramics is strongly influenced by the molecular organization of the starting precursors. The presence of siloxane rings in the cyclic-derived polysiloxane decreases the stability of the amorphous SiO2 and promotes the crystallization of cristobalite.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 356, Issue 3, 1 February 2010, Pages 132–140
نویسندگان
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