کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1487041 1510692 2016 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Copper(I) sulfide (Cu2S) nanoparticles from Cu(II) diethyldithiocarbamate: Synthesis, characterization and its application in ultrasound-assisted catalytic degradation of organic dye pollutants
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Copper(I) sulfide (Cu2S) nanoparticles from Cu(II) diethyldithiocarbamate: Synthesis, characterization and its application in ultrasound-assisted catalytic degradation of organic dye pollutants
چکیده انگلیسی


• The Cu2S nanoparticles were prepared by a one-step thermal decomposition.
• The Cu2S nanoparticles were used as a stable and recoverable sonocatalyst.
• The Cu2S nanoparticles exhibit excellent H2O2-assisted sonocatalytic activity.
• MB dye was degraded within short time over the Cu2S nanoparticles.

In this study, copper(I) sulfide (Cu2S) nanoparticles were easily synthesized via thermal decomposition of Cu(II) diethyldithiocarbamate complex at 220 °C. Characterization by a variety of spectroscopic and physical techniques confirmed that the obtained product was pure Cu2S composed of about 50 nm nanoparticles. An ultrasound-assisted advanced oxidation process (AOP) was developed for the degradation of methylene blue (MB) over the Cu2S nanoparticles. The ultrasound-assisted H2O2/Cu2S catalysis removed 100% MB (25 mg L−1) in 12 min with an apparent rate constant of 0.268 min−1, which is 193 and 27.5 folds of that in the simple catalytic H2O2/Cu2S and US/H2O2 systems, respectively. The synergistic behavior between Cu2S catalysis and ultrasound waves was demonstrated to be dependent on Cu2S dosage and H2O2 concentration. Trapping experiments indicated that OH radicals were the main reactive species for MB degradation in the present sonocatalytic system. Furthermore, the cycling experiments revealed the good stability of Cu2S nanoparticles.

Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 83, November 2016, Pages 345–353
نویسندگان
, ,