کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1487293 1510705 2015 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Microstructural features of the La1−xCaxFeO3−δ solid solutions prepared via Pechini route
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Microstructural features of the La1−xCaxFeO3−δ solid solutions prepared via Pechini route
چکیده انگلیسی


• La1−xCaxFeO (3−δ) (0 ≤ x ≤ 0.7) perovskite were prepared by Pechini method.
• Planar defects in direction (1 0 1) were observed in the perovskite surface.
• α-Fe2O3 particles (1–10 nm) on the surface of perovskite were revealed.
• Amount of α-Fe2O3 particles on the perovskite surface grew with rising x values.

Solid solutions with La1−xCaxFeO3−δ (0 ≤ x ≤ 0.7) perovskite-like structure prepared via Pechini route have been investigated by using high resolution transmission electron microscopy and X-ray diffraction. Extended planar defects lying in (1 0 1) crystallographic planes and α-Fe2O3 nanoparticles on the surface of perovskite microcrystals are characteristic of the samples under investigation. It was found that testing of the samples in catalytic deep CH4 oxidation process results in partial destruction of solid solutions with formation of planar defects in the bulk and α-Fe2O3 particles on the surface.

Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 70, October 2015, Pages 291–295
نویسندگان
, , ,