Luminescence properties and electronic structure of Ce3+-doped gadolinium aluminum garnet

• The luminescence properties of Ce3+ ions in (Y, Gd)3Al5O12 are analyzed.
• The Gd3+ → Y3+ substitution leads to increasing of Ce3+ noncubic crystal field splitting parameter.
• The excitation spectra for the Ce3+ emission in GdAG contain bands at 6.67, 7.75, and 9.76 eV.
• These features are due to the Ce3+-bound exciton formation and O 2p → Al 3s, 3p transitions.
• Contributions from Al atoms to the conduction-band density of states are quite essential.

Yttrium-gadolinium aluminum garnets (YGdAG) doped with Ce3+ ions have been prepared by co-precipitation method. The luminescent properties of Ce3+ ions in Gd3(1−x)Ce3xAl5O12 (х = 0.01) have been studied upon excitation in the 2–20 eV region. The substitution of Gd3+ for Y3+ in the garnet structure results in broadening the emission band and shifting its maximum towards the longer wavelengths. It was found that in addition to the 4f → 5d excitation bands of Ce3+ ions, the excitation spectra for the Ce3+ emission contain bands at 6.67, 7.75, and 9.76 eV. These bands are attributed to the Ce3+-bound exciton formation and O 2p → Al 3s, 3p transitions, respectively. Although gadolinium states dominate near the bottom of the conduction band of Gd3Al5O12, contributions from Altetr and Aloct atoms to the conduction-band density of states are evaluated as quite essential.

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