Photoluminescence and thermoluminescence properties of Tb3+ doped K3Gd(PO4)2 nanophosphor

• First time, a detailed TL and PL study on undoped and Tb3+ doped K3Gd(PO4)2 nanophosphor.
• Combustion method was employed to synthesize the Tb3+ doped K3Gd(PO4)2 nanophosphor.
• Mechanism of excitation and emission in undoped and Tb3+ doped K3Gd(PO4)2 nanophosphor was given.

Tb3+ doped nanoparticulate K3Gd(PO4)2 phosphor was prepared by combustion method using urea as a fuel. The structure, optical and luminescent properties of the phosphor were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM), diffuse reflectance spectroscopy (DRS), photoluminescence spectroscopy (PL), and thermoluminescence (TL) spectroscopy. In undoped K3Gd(PO4)2, the excitation and emission peaks at 273 nm and 323 nm belongs to the 8S7/2 → 6IJ(J = 7/2) and 6PJ(J = 7/2) → 8 S7/2 transitions of Gd3+ while green emission was observed in the Tb3+ doped K3Gd(PO4)2. TL study was carried out after exposing the samples to γ-radiations (0.1–5 kGy) in the K3Gd(PO4)2:Tb3+ (1.5 mol%). The calculated kinetic parameters were compared with different methods. The band gap of the phosphor was estimated as 5.80 eV. The green shade of the Tb3+ ion with the CIE coordinates (x, y) as (0.29, 0.54) was in good agreement with the well known green phosphors.

Figure optionsDownload as PowerPoint slideEnergy level diagram of Tb3+ ion in the K3Gd(PO4)2 host lattice.