Solvothermal synthesis in ethylene glycol and adsorption property of magnetic Fe3O4 microspheres

• Fe3O4 microspheres (ca. 0.34 μm) were made under optimized solvothermal conditions.
• The optimized formula is significantly cost-saving and waste-reducing.
• Upon EDTA modification, Fe3O4 microspheres adsorb 4.5–7.9 mg Cu2+/g.

Monodisperse Fe3O4 microspheres have great potential in many fields, including magnetic separation, drug delivery and catalysis. In the present work, we first investigated various parameters affecting solvothermal synthesis of Fe3O4 microspheres in ethylene glycol (MEG), and then successfully synthesized magnetic Fe3O4 microspheres of ca. 0.34 μm by treatment of the concentrated mixture of FeCl3·6H2O (13.7 mmol) and NaOAc (43.9 mmol) in 9 ml of MEG at 198 °C for 14 h. This formula significantly reduces the production cost of Fe3O4 microspheres and the resulting waste. Upon ethylenediamine tetraacetate (EDTA) modification, the Cu2+ adsorption capacity of Fe3O4 microspheres obviously increases from negligible to 4.5–7.9 mg/g. In combination with EDTA as a versatile chelating agent, EDTA-modified Fe3O4 microspheres are potential magnetic adsorbents for removal of trace heavy metal ions from waste water.

Magnetic Fe3O4 microspheres of ca. 0.34 μm have been successfully synthesized by heat treatment of the concnentrated mixture of FeCl3·6H2O (13.7 mmol), NaOAc (43.9 mmol) in 9 ml of MEG at 198 °C for 14 h. This formula significantly reduces the production cost of Fe3O4 microspheres and the resulting waste. Upon EDTA modification, the Cu2+ adsorption capacity of Fe3O4 microspheres obviously increases from negligible to 4.5–7.9 mg/g.Figure optionsDownload as PowerPoint slide