Synthesis of BiOI flowerlike hierarchical structures toward photocatalytic reduction of CO2 to CH4

• Room temperature synthesis of BiOI flowerlike hierarchical structures.
• BiOI can be used for photocatalytic reduction of CO2 into hydrocarbon fuels under sunlight.
• The photocatalytic activity of BiOI is higher than that of P25 TiO2.

BiOI flowerlike hierarchical structure was synthesized by the direct hydrolysis method – hydrolysis at room temperature in the presence of polyvinyl pyrrolidone. As-synthesized BiOI was characterized by powder X-ray diffraction, UV–vis diffuse reflectance spectra, X-ray photoelectron spectroscopy spectra, scanning electron microscopy, transmission electron microscopy, and high-resolution transmission electron microscopy. It is a facile way to obtain BiOI flowerlike hierarchical structure photocatalyst for photocatalytic reduction of CO2 into hydrocarbon fuels under simulated sunlight irradiation without cocatalyst. And the photocatalytic activity of as-synthesized BiOI is higher than that of P25 TiO2 and bulk BiOI.

Figure optionsDownload as PowerPoint slideBiOI can be used for photocatalytic reduction of CO2 into hydrocarbon fuels under sunlight.