Synthesis, characterization, and catalytic application of ordered mesoporous carbon–niobium oxide composites

• Ordered mesoporous carbon–niobium oxide composites were synthesized.
• The content of Nb2O5 in the composites could be tuned from 38 to 75%.
• Niobium species were highly dispersed in amorphous carbon framework walls.
• The composites exhibited good catalytic performance in the dehydration of fructose.

Ordered mesoporous carbon–niobium oxide composites have been synthesized by a multi-component co-assembly method associated with a carbonization process using phenolic resol as carbon source, niobium chloride as precursor and amphiphilic triblock copolymer Pluronic F127 as template. The resulting materials were characterized using a combination of techniques including differential scanning calorimetry–thermogravimetric analysis, N2 physical adsorption, X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy. The results show that with increasing the content of Nb2O5 from 38 to 75% the specific surface area decreases from 306.4 to 124.5 m2 g−1, while the ordered mesoporous structure is remained. Niobium species is well dispersed in the amorphous carbon framework. The mesoporous carbon–niobium oxide composites exhibit high catalytic activity in the dehydration of fructose to 5-hydroxymethylfurfural. A 100% conversion of fructose and a 76.5% selectivity of 5-hydroxymethylfurfural were obtained over the carbon–niobium oxide composite containing 75% Nb2O5 under the investigated reaction conditions.

The ordered mesoporous carbon–niobium oxide composites have been synthesized by a multi-component co-assembly method associated with a carbonization process.Figure optionsDownload as PowerPoint slide