کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1488225 1510724 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A novel Bi-based phosphomolybdate photocatalyst K2Bi(PO4)(MoO4): Crystal structure, electronic structure and photocatalytic activity
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
A novel Bi-based phosphomolybdate photocatalyst K2Bi(PO4)(MoO4): Crystal structure, electronic structure and photocatalytic activity
چکیده انگلیسی


• A new type of phosphomolybdate K2Bi(PO4)(MoO4) photocatalyst was successfully synthesized.
• The products synthesized at 600 °C were mainly composed of nano-cubes.
• The indirect band gap of K2Bi(PO4)(MoO4) has been determined to be 2.93 eV.
• K2Bi(PO4)(MoO4) synthesized at 600 °C exhibits the highest photocatalytic activity.
• The electronic structure was calculated by density functional calculations.

A novel phosphomolybdate photocatalyst K2Bi(PO4)(MoO4) has been successfully developed via a solid-state reaction. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), diffuse reflectance spectrum (DRS) and photoluminescence (PL) spectra. The photocatalytic activities of the samples prepared at different temperature were determined by the photooxidative decomposition of methylene blue (MB) in aqueous solution. The results revealed that K2Bi(PO4)(MoO4) can be used as an effective photocatalyst under UV–vis irradiation and the nanocubes obtained at 600 °C exhibits the highest photocatalytic activity. The photodegradation of MB by K2Bi(PO4)(MoO4) nanocrystals followed the first-order kinetics. Theoretical calculations on electronic structure confirmed the indirect optical transitions property in the absorption edge region of K2Bi(PO4)(MoO4), and the orbital constitutions of CB and VB were also analyzed.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 51, March 2014, Pages 455–459
نویسندگان
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