In-situ growth of zinc tungstate nanorods on graphene for enhanced photocatalytic performance

• Graphene–ZnWO4 composite photocatalyst was prepared for the first time.
• The as-prepared composite photocatalysts show high activity for dye degradation.
• Effect of graphene amount on the photocatalytic activity was investigated.

Graphene–zinc tungstate (G–ZnWO4) hybrid photocatalysts were prepared by an in-situ growth method in which the reduction of graphene oxide (GO) and the growth of ZnWO4 crystals occurred simultaneously. The materials were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, UV–vis diffuse reflectance spectroscopy and X-ray photoelectron spectroscopy. The photocatalytic activity was investigated by the degradation of dye methylene blue (MB). An enhancement in the photocatalytic activity was observed for G–ZnWO4 hybrids compared with pure ZnWO4 under UV light. This improvement was attributed to the following two reasons: increased migration efficiency of photo-induced electrons and increased adsorption activity for dye molecules. The effect of the amount of graphene on the photocatalytic activity was also investigated. Results showed that there was an optimum amount of 2%.

Graphene/ZnWO4 (G–ZnWO4) nanorod composite photocatalysts were prepared by a simple one-step method. Namely, the reduction of graphene oxide and the growth of ZnWO4 nanorod occurred simultaneously in one single process. An enhancement in the photocatalytic activities were observed in G–ZnWO4 composites compared with pure ZnWO4 under UV light irradiation.Figure optionsDownload as PowerPoint slide