کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1488257 1510718 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Growth and characterization of kesterite Cu2ZnSn(SxSe1 − x)4 crystals for photovoltaic applications
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Growth and characterization of kesterite Cu2ZnSn(SxSe1 − x)4 crystals for photovoltaic applications
چکیده انگلیسی


• Cu2ZnSn(SxSe1 − x)4 crystals were grown using vertical gradient freeze technique.
• Grown CZTSSe crystals exhibited highly crystalline tetragonal kesterite structure.
• Grown ingot showed a homogeneous, stoichiometric composition along the growth axis.
• Cu-rich particulates were observed along the polycrystalline grain boundaries.
• Large volume of high quality CZTSSe can be grown using this novel VGF method.

Cu2ZnSn(SxSe1 − x)4 (CZTSSe) bulk crystals have been grown for the first time, in multi-gram quantities, using a novel vertical gradient freeze (VGF) technique. Large grain polycrystalline CZTSSe ingot with grain sizes ∼0.2–0.5 mm was grown in a vacuum sealed quartz ampoule. Structural, compositional, and electronic properties of the ingot were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), energy dispersive X-ray spectroscopy (EDS), and van der Pauw measurements. XRD analysis showed highly crystalline tetragonal structure corresponding to kesterite CZTSSe with lattice constants of a = 5.563 Å, and c = 11.09 Å (c/2a = 0.997) and Raman spectra confirmed the formation of single phase CZTSSe. High-resolution XPS spectra confirmed the formation of metal-sulfoselenides. The ingot along the growth axis showed a homogeneous near stoichiometric elemental distribution corresponding to Cu/(Zn + Sn) = 0.94 and Zn/Sn = 0.98. EDS mapping on the ingot's outer surface revealed formation of islanded Cu-rich droplets at the grain boundaries. Grown crystals exhibited p-type conductivity with a measured bulk resistivity of ∼51 Ω cm.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 57, September 2014, Pages 135–139
نویسندگان
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