کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1488277 1510718 2014 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Physical and electrochemical properties of spherical Li[Li0.2Mn0.44Ni0.18Co0.18]O2/MnO2 composite as a cathode for rechargeable lithium-ion battery
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Physical and electrochemical properties of spherical Li[Li0.2Mn0.44Ni0.18Co0.18]O2/MnO2 composite as a cathode for rechargeable lithium-ion battery
چکیده انگلیسی


• Li[Li0.2Mn0.44Ni0.18Co0.18]O2/MnO2 composite was synthesized by incorporation of MnO2 into spherical Li[Li0.2Mn0.44Ni0.18Co0.18]O2.
• Properties of spherical Li-rich layered oxide can be greatly improved by adding MnO2.
• The reason for the improvement of Li[Li0.2Mn0.44Ni0.18Co0.18]O2/MnO2 by adding MnO2 was explained.

Spherical Li-rich layered Li[Li0.2Mn0.44Ni0.18Co0.18]O2 with high tap density and low specific surface area was synthesized. Furthermore, low cost and environmental benign MnO2 was blended into it and Li[Li0.2Mn0.44Ni0.18Co0.18]O2/MnO2 composite was obtained. The properties of the materials were investigated by XRD, SEM and electrochemical method. The results showed that the existence of MnO2 in the composites can't change the structure of the pristine Li[Li0.2Mn0.44Ni0.18Co0.18]O2. The electrochemical characteristics of Li[Li0.2Mn0.44Ni0.18Co0.18]O2/MnO2 such as the initial coulombic efficiency, discharge capacity, rate characteristics and cyclability are much better than those of the pristine Li[Li0.2Mn0.44Ni0.18Co0.18]O2. The contribution of MnO2 to the excellent characteristics of the cathode is as follows: the existence of MnO2 (i) provides more active site for lithiation/delitiation and (ii) suppresses side interaction between cathode particle surface and electrolyte.

MnO2 was blended into pristine Li[Li0.2Mn0.44Ni0.18Co0.18]O2 and Li[Li0.2Mn0.44Ni0.18Co0.18]O2/MnO2 composite was obtained. We can observe that the adding MnO2 in the composite participates in the electrochemical reaction and provide more active sites for lithiation/delithiation.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 57, September 2014, Pages 274–279
نویسندگان
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