کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1488313 1510717 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Temperature and interfacial buffer layer effects on the nanostructure in a copper(II) phthalocyanine: Fullerene bulk heterojunction
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Temperature and interfacial buffer layer effects on the nanostructure in a copper(II) phthalocyanine: Fullerene bulk heterojunction
چکیده انگلیسی


• Real time variation of CuPc:C60 nanostructure was investigated by X-ray scattering.
• The growth temperature affected the formation of standing γ(2 0 0) CuPc.
• The lying down CuPc phase was formed in BHJ layer by the insertion of CuI.
• ATD was effective on a large amount of the lying down CuPc phase in the BHJ layer.

The effects of the temperature and the presence of an interfacial buffer layer on the nanostructure of organic bulk heterojunctions (BHJs) based on copper phthalocyanine (CuPc) and fullerene (C60) systems were examined using real-time in situ X-ray measurements. The CuPc:C60 BHJ structures prepared without a buffer layer formed a standing-on configured γ-CuPc phase. Once formed, the γ-phase could be rendered thermally stable by post-annealing at 180 °C. The insertion of a CuI buffer layer prior to the deposition of a CuPc:C60 BHJ layer induced the formation of a lying-down configured CuPc phase in the BHJ layer. The CuPc peak intensity and lattice parameters gradually increased upon thermal annealing. This increase in intensity appeared to be related to the strain at the interface between the CuPc:C60 and CuI layers.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 58, October 2014, Pages 102–106
نویسندگان
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