کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1488327 | 1510717 | 2014 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Surface modification of Li[Li0.2Ni0.2Mn0.6]O2 nanoparticles with polydopamine-assisted MgF2 coating Surface modification of Li[Li0.2Ni0.2Mn0.6]O2 nanoparticles with polydopamine-assisted MgF2 coating](/preview/png/1488327.png)
• A surface of the nano-sized Li[Ni0.2Li0.2Mn0.6]O2 was modified by MgF2 coating.
• A polydopamine pre-coating layer served as a binding agent for the homogeneous coating.
• Polydopamine-assisted MgF2 coating improved the electrochemical property of the cathode.
Nano-sized Li[Ni0.2Li0.2Mn0.6]O2 powder is vulnerable to reaction with the electrolyte because it has a wide electrolyte/cathode contact area. In order to avoid this, we modified the surface of the nano-sized Li[Ni0.2Li0.2Mn0.6]O2 powder by coating it with MgF2. A polydopamine pre-coating layer served as a binding agent for the homogeneous MgF2 coating on the surface of the Li[Ni0.2Li0.2Mn0.6]O2 nanoparticles. Polydopamine-assisted coating with MgF2 improved the discharge capacity, cyclic performance and thermal stability of the Li[Ni0.2Li0.2Mn0.6]O2 cathode, possibly by suppressing side reactions between the electrolyte and the cathode.
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Journal: Materials Research Bulletin - Volume 58, October 2014, Pages 169–173