کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1488339 | 1510717 | 2014 | 6 صفحه PDF | دانلود رایگان |
• The cathode material synthesized by co-precipitation using a Couette–Taylor reactor.
• The first and second discharge capacities were measured to be 311 and 307 mA h g−1.
• The material has an excellent rate capability.
The 0.34Li2MnO3·0.66LiMn0.63Ni0.24Co0.13O2 cathode material for the Li-ion battery is synthesized by co-precipitation using a Couette–Taylor reactor. Particle size analysis (PSA) and a field emission-scanning electron microscopy (FE-SEM) images show that the obtained precursor and cathode material exhibit a narrow particle size distribution and spherical shape. The structure and composition of the 0.34Li2MnO3·0.66LiMn0.63Ni0.24Co0.13O2 are confirmed by X-ray diffraction (XRD) and inductively coupled plasma atomic emission spectroscopy (ICP-AES). The first and second discharge capacities of 0.34Li2MnO3·0.66LiMn0.63Ni0.24Co0.13O2 are measured to be 311 and 307 mA h g−1, respectively. The material also has an excellent rate capability (250 and 180 mA h g−1 at 1 C and 5 C, respectively). In the rate capability test at 60 °C, 0.34Li2MnO3·0.66LiMn0.63Ni0.24Co0.13O2 has a higher capacity of over 210 mA h g−1 in the range 0.1–10 C. In the cyclic performance test, the capacity retention at high temperature is over 85% after 50 cycles, which is similar to that at room temperature. The 0.34Li2MnO3·0.66LiMn0.63Ni0.24Co0.13O2 is therefore a high-capacity material with potential for use as an electrode in Li-ion batteries.
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Journal: Materials Research Bulletin - Volume 58, October 2014, Pages 223–228