کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1488504 | 1510725 | 2014 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Fabrication and high temperature thermoelectric properties of c-axis oriented Na0.68CoO:Ag nanocomposite thin films Fabrication and high temperature thermoelectric properties of c-axis oriented Na0.68CoO:Ag nanocomposite thin films](/preview/png/1488504.png)
• c-Axis oriented Na0.68CoO2:Ag composite thin films with nanosized Ag particles well dispersed in the Na0.68CoO2 matrix have been fabricated.
• The power factor of Na0.68CoO2/5 wt.% Ag nanocomposite thin film is about 2 times higher than that of the Ag-free film.
• Adding metallic nanoinclusions is a promising way to improve the thermoelectric performance of NaxCoO2 films.
c-Axis oriented Na0.68CoO2:Ag composite thin films with metallic Ag nanoparticles embedded in the Na0.68CoO2 matrix have been fabricated by post-annealing the PLD-grown CoO:Ag precursor film in Na vapor at high temperatures. The nanosized Ag inclusions can greatly improve the electrical conductivity while retaining the Seebeck coefficient of Na0.68CoO2 films, resulting in an enhanced power factor. The power factor of the 5.0 wt.% Ag-added Na0.68CoO2 films reaches 1.85 mW/m K2 at 800 K, which is about 2 times higher than that of Ag-free films. Moreover, the thermal conductivity in these nanocomposite films is expected to be suppressed due to the enhanced phonon scatterings on nanoinclusions. The results demonstrated that adding Ag nanoinclusions is an effective way to improve the thermoelectric performance of NaxCoO2 films.
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Journal: Materials Research Bulletin - Volume 50, February 2014, Pages 161–164