The Effect of Ca–Zr mole ratio on preparation, structural and magnetic properties of Ca–Zr doped Bi-YIG

• Ca–Zr substituted Bi-YIG has been prepared via mechanochemical processing and heat treatment.
• Structural and magnetic properties were investigated.
• Magnetic measurements showed the Ferrimagnetic behavior for pure garnet structure samples.
• The spherical morphology of the nanoparticles was found from the SEM micrograph.

Ca–Zr substituted (Bi-YIG) nanopowders with a nominal composition of BiY2−xCaxZryFe5−yO12 (x = y and x varied from 0.00 to 1.25 by the step of 0.25) were prepared by mechanochemical processing (MCP) and subsequent heat treatments. The effect of dopant mol ratios, on garnet phase formation were investigated by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy. The lattice constant of the samples increased by increasing Zr4+ content (for x ≤ 1). Mean crystallite size of the single-phase powders, which was evaluated by Scherrer's formula, was about 35 nm. The experimental results show that the Ca–Zr substitution Bi-YIG lowers the calcining and sintering temperatures for x < 1. The results show that the single-phase nanopowders can be obtained at temperatures below 850 °C. The measurements of vibrating sample magnetometer (VSM) show that the saturation magnetization of the samples increases as x increase from 0.00 to 0.25 and then decreases by increasing x to the values greater than 0.25.

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