کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1489272 992303 2013 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influences of urea–glycerol mixtures as mixed mesopore-controlling agents on tailoring physicochemical properties and photocatalytic H2 production activity of sol–gel-derived mesoporous-assembled TiO2 nanocrystals
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Influences of urea–glycerol mixtures as mixed mesopore-controlling agents on tailoring physicochemical properties and photocatalytic H2 production activity of sol–gel-derived mesoporous-assembled TiO2 nanocrystals
چکیده انگلیسی

In this work, the mesoporous-assembled TiO2 nanocrystal photocatalysts were successfully synthesized by a sol–gel process with the aid of urea–glycerol mixtures used as mixed mesopore-controlling agents. The photocatalytic activity of the synthesized mesoporous-assembled TiO2 nanocrystal photocatalysts was investigated for hydrogen production from the water splitting reaction using methanol as a hole scavenger under UV light irradiation. The synthesized TiO2 nanocrystal photocatalysts were systematically characterized by TG–DTA, N2 adsorption–desorption, SEM, high resolution TEM, and XRD analyses. The characterization results showed that the well-controlled contents of urea and glycerol in a urea–glycerol mixture at 75 mol% urea and 25 mol% glycerol resulted in not only the most highly porous network (i.e. the highest specific surface area and total pore volume, and the smallest mean mesopore diameter), but also the smallest crystallite size of the synthesized TiO2 nanocrystal photocatalyst. The photocatalytic reaction results, hence, revealed a much superior photocatalytic hydrogen production activity of the mesoporous-assembled TiO2 nanocrystal synthesized with 75 mol% urea and 25 mol% glycerol to the other synthesized TiO2 nanocrystals, also being much higher than those of the commercially available P-25 TiO2 and ST-01 TiO2 powders.

Figure optionsDownload as PowerPoint slideHighlights
► Mesoporous-assembled TiO2 nanocrystals were synthesized by modified sol–gel process.
► Urea–glycerol mixtures were applied as mixed mesopore-controlling agents.
► Urea and glycerol contents affected physicochemical properties of synthesized TiO2.
► Photocatalytic H2 production activity also depended on urea and glycerol contents.
► 75 mol% urea and 25 mol% glycerol yielded the most photocatalytically active TiO2.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Research Bulletin - Volume 48, Issue 1, January 2013, Pages 30–36
نویسندگان
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