Synthesis of mesoporous TS-1 using a hybrid SiO2–TiO2 xerogel for catalytic oxidative desulfurization

Mesoporous TS-1 (M-TS-1) was synthesized using a hybrid SiO2–TiO2 xerogel combined with an organosilane precursor. Prepared samples were characterized by XRD, UV–vis spectroscopy, SEM, and N2 adsorption–desorption measurement. M-TS-1, prepared in 2 days, showed high crystallinity and the best textural properties among the samples. The N2 adsorption–desorption isotherms of M-TS-1 exhibited a hysteresis loop at pressure higher than P/P0 = 0.4, clearly indicating the existence of mesopores. M-TS-1 has significantly larger mesopore volume (0.48 cm3/g) than that of conventional TS-1 (0.07 cm3/g), and showed a narrow peak centered at ca. 6.3 nm. In the oxidative desulfurization reaction, M-TS-1 was more active than conventional TS-1 at the same Ti-loading; M-TS-1 produced a dibenzothiophene (DBT) conversion of 96%, whereas conventional TS-1 produced a final DBT conversion of 5.6% after a reaction time of 180 min. Oxidative desulfurization over TS-1 was influenced both by electron density and steric hindrance in the sulfur compounds tested.

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► Meso-TS-1 catalyst was synthesized using a SiO2–TiO2 xerogel with an organosilane precursor.
► Hierarchical pore structure was confirmed by characterization of the materials.
► Catalytic activity was tested using oxidative desulfurization of the model sulfur compounds.
► Meso-TS-1 demonstrated significantly improved catalytic activity than TS-1.